Tuesday, August 4, 2015

Petroleum—The Black Gold Underground

From the second industrial revolution till now, petroleum is immensely important resources
to human society. As the mixture of organic chemicals. It play a role as blood to industries. And in daily life we are even more relying on petroleum and its products. The running car, plastic we use and the asphalt road we drive on and so on. But what is petroleum? why is it so important?


  one of the most important product of petroleum is plastic. Nowadays plastic is the most common material in daily due to their relatively low cost, ease of manufacture, versatility, and imperviousness to water. They have already displaced many traditional materials, such as wood, stone, horn and bone, leather, paper, metal, glass, and ceramic, in most of their former uses. 



And the industries usage of plastic is also wild. From strong, chemical- and heat-resistant thermoplastic to biocompatibility. deadpans on the purpose of the usage。










Second one is fuel. This is the blood for modern society. 
Most common petroleum's fuel product  are gasoline, kerosene, heavy crude oil and diesel. Most of vehicles burn gasoline in order to run. Airplanes needs jet fuel. some power plants use petroleum to produce electricity in some area. As the world is globalized. The demand of fuel is getting stronger and stronger. Our environment also face a great danger due to greenhouse gases. But till now we don't have any other resources that can replace petroleum.



Petroleum is the mixture mainly consists various kinds of Alkanes; Naphthalene and Aromatic Hydrocarbon. In smaller view It mainly constitute by carbon and hydrogen. Around 83%~87% is carbon, 10 %~14% hydrogen there are also Oxygen, nitrogen and sulfur but the content is less than 1%. It is oily liquid Which is usually dark brown, brownish black, blackish green and sometime transparent. 

The formation of petroleum requires at least 2 million years. It also requires a suitable environment for ancient organic materials, such as zooplankton and algae to form petroleum. 

Petroleum is a amazing mixture of chemicals indeed.

How Does Soap Clean Us?





            Soaps are sodium or potassium fatty acids salts, produced from the hydrolysis of fats in a chemical reaction called saponification. Each soap molecule has a long hydrocarbon chain, sometimes called its 'tail', with a carboxylate 'head'. In water, the sodium or potassium ions float free, leaving a negatively-charged head.
        Soap is an excellent cleanser because of its ability to act as an emulsifying agent. An emulsifier is capable of dispersing one liquid into another immiscible liquid. This means that while oil (which attracts dirt) doesn't naturally mix with water, soap can suspend oil/dirt in such a way that it can be removed. Natural soaps are sodium or potassium salts of fatty acids, originally made by boiling lard or other animal fat together with lye or potash (potassium hydroxide). Hydrolysis of the fats and oils occurs, yielding glycerol and crude soap.

In the industrial manufacture of soap, tallow (fat from animals such as cattle and sheep) or vegetable fat is heated with sodium hydroxide. Once the saponification reaction is complete, sodium chloride is added to precipitate the soap. The water layer is drawn off the top of the mixture and the glycerol is recovered using vacuum distillation.
The organic part of a natural soap is a negatively-charged, polar molecule. Its hydrophilic (water-loving) carboxylate group (-CO2) interacts with water molecules via ion-dipole interactions and hydrogen bonding. The hydrophobic (water-fearing) part of a soap molecule, its long, non-polar hydrocarbon chain, does not interact with water molecules. The hydrocarbon chains are attracted to each other by dispersion forces and cluster together, forming structures called micelles. In these micelles, the carboxylate groups form a negatively-charged spherical surface, with the hydrocarbon chains inside the sphere. Because they are negatively charged, soap micelles repel each other and remain dispersed in water.

A soap micelle has a hydrophilic head that is in contact with the water and a center of hydrophobic tails, which can be used to isolate grime.

Although soaps are excellent cleansers, they do have disadvantages. As salts of weak acids, they are converted by mineral acids into free fatty acids:
CH3(CH2)16CO2-Na+ + HCl  CH3(CH2)16CO2H + Na+ + Cl-
These fatty acids are less soluble than the sodium or potassium salts and form a precipitate or soap scum. Because of this, soaps are ineffective in acidic water. Also, soaps form insoluble salts in hard water, such as water containing magnesium, calcium, or iron.
2 CH3(CH2)16CO2-Na+ + Mg2+  [CH3(CH2)16CO2-]2Mg2+ + 2 Na+
The insoluble salts form bathtub rings, leave films that reduce hair luster, and gray/roughen textiles after repeated washing. Synthetic detergents, however, may be soluble in both acidic and alkaline solutions and don't form insoluble precipitates in hard water. But that is a different story…

Monday, August 3, 2015

Graphene is so cool!

Googling something has never made me so as excited as these 8 letters in this particular order. I wanted to blog about life changing chemicals that are already making our world better, but I wanted to be different and share with my friends something theoretical! Theoretical chemistry! 
Let’s start at the beginning; reader, meet graphite:
The lead in your pencil, the contacts in your electric motor, and one day the key to your future! 
The hexagonal honeycomb layers you see made of blue spheres and solid black lines is the pure strength of nature. Its chemistry telling us to know our place and keep quiet. Those layers are 200 times stronger than man made steel, and occur naturally in the form of coal. 
There is a reason we don’t make skyscrapers out of charcoal though. Unfortunately graphite has a hidden weakness. The solid lines represent very strong covalent bonds. You can put your faith in those, in fact most of the bonds between chemicals in your body are made of those, so that’s fine. What not cool is the dashed lines between the hexagon layers. Whilst covalent bonds are INTERmolecular bonds, the separate layers of graphite are held together by induced dipoles, which are INTRAmolecular bonds. Think of the difference between the intermolecular bonds and intramolecular bonds similar to welding two sheets of metal together and asking them nicely to stay put! 
So why not keep the cool part and work with that instead? Of course, we’ve done it. In 2008 scientists Andre Geim and Konstantin Novoselov (now both winners of Nobel Prizes, knighted sirs of the United Kingdom and chemistry rock starts) solved the centuries old problem of isolating a single layer of graphite by sticking a piece of scotch tape to a sample, and ripping it off. What was stuck to the bottom of that tape was pure gold in terms of chemistry (pun intended). Sir Geim and Novoselov thought so far outside the box the box disappeared over the horizon, and a new horizon of possibilities is just around the corner. Just like how plastics revolutionized the world in the 20th century, the 21st century might have its new plastic. Hooray for hydrocarbons! 
So what’s so great about graphene? Well here’s a list:
It’s the world’s first 2D object; only extending in the latitudinal and longitudinal planes.
Its conductive because of a field of delocalized electrons 
It’s super hard and strong 
And it’s incredibly easy to make and manufacture, since all you need is layers of graphene and your imagination. 
And that’s what we’re working with. Let’s see what minds greater than us have come up with regarding graphene:
Biomedical 
When graphene is oxidized it is a great stock molecule that is a base from which to further functionalize the graphene molecule to make it more specific for a certain job. The oxidized graphene is called GO colloquially. 
These GO molecules are on a scale of nanometers, with 1-3 layers being just 2 nanometers thick (or 2x10-9 m thick OR 0.0000000009 meters). 
GO that has carboxylic acid (COOH) and hydroxyl (OH) functional groups are said to be very ‘biocompatible’, meaning our bodies can easily work with these molecules. And moreover, those groups mentioned up there can be the ‘docks’ to which many drugs and medical concoctions are attached, then introduced to the body via means that can be less invasive than before.
One greatly promising future application of this technology is in cancer treatment. GO molecules can be ‘loaded’ with multiple drugs which to my understanding bombard the cancer with an array of substances designed to harm only the bad cells. Beforehand the payload could only be administered the old fashioned way; through injections (less direct) and an intake of pills (VERY indirect). I guess you could say the current (hopefully soon to old) methods are like carpet bombing the targeted cells and everything around it whereas GO delivery systems will be similar to a precision SWAT team strike. 
Energy 
Now let’s fly away from the topic of cancer, and talk about our worldwide energy crisis…in our phones. 
Battery and portable power supply technology hasn’t actually advanced very far ever since the 1960s! Lithium ion batteries made huge advancements during his period and we have been gradually making things slightly better until now, but no breakthrough or big leap as we have had with the actual things being run off of those batteries since then (think about the brick phones of the 70s to the iPhones of 2007! Just take out the b, r, c and the k). 
Thankfully there’s graphene to the rescue. For a good power source to work it needs to have the best of the following features:
High volume
High surface area
Conductive
Chemically and physically stable
Low weight
This reminds me of graphene. The high volume and surface area is essential. 
The amount of charge (or ‘power’) a battery can have is a function of its volume. Think of the charge as the air in a balloon. Big balloon = lots of air ≃ lots of power (and a bigger fright when someone pops it). 
And the surface area describes how fast the battery will discharge and can recharge. It’s like how you will lose heat a lot faster in winter if you expose more surface area of your skin (that’s proven already, don’t go and test it out). 
So graphene is doubly, triply and singlehandedly the best material we currently have for building next gen batteries. 
Even better, researchers predict future cells can actually be modular; you can make batteries for larger and larger machines just by slapping more and more cells  together until you’ve got one big enough to power whatever you need to work. Imagine if one graphene cell was a LEGO brick, its cuboidal has its own volume and surface area. You can stick one hundred together to make a cell phone battery or one thousand to make a power source for an electric car! See how the volume and S.A. increases linearly, making bigger batteries more powerful, easier to discharge, and better suited to their job automatically? This is an almost too perfect system to power our future!
Technology
In the future we’ll be injecting ourselves with graphene and charging ourselves with it. But how about wearing it?
Wearable technology is a new emerging market that has a strong foothold all over the world. From Jawbones to iWatches, funny names and incredible electronics are abound, improving our wellbeing, for example by allowing doctors who use Google Glass to quickly read patient history and data to better diagnose and help them, to giving us luxuries, like the Jabra wireless earphones that have built in heart rate monitors.
Where in the world do we go from here? Smaller.
As we’ve seen before graphene can be forged into so many different shapes and sizes due to its simplistic structure. The electronics industry has always been working towards the tiniest dimensions possible to allow a device to accommodate more features. 
Since graphene can essentially be worked from the size of a carbon atom upwards, there are no limits, since we are already staring at the limit. 
Firstly, more processing power than ever is possible because of graphene’s conductivity. Transistors and highly advanced microchips (perhaps we will start calling them nanochips) can multiply the amount of data being processed exponentially, and if you need even more, just plug some additional components in there. 

The difference between 1 GB of storage space 25 years ago and now. The device that holds 1 GB in the future probably can’t even be viewed by the human eye. 
Secondly, graphene is very flexible. This could potentially allow flexible and fully functional electronic screens. 
Combining this with minuscule processors even means you could have a computer and a screen all in one. 
Imagine camping in the future. Instead of a traditional map, you could get ones that are actually an entire screen, with built-in features like GPS to keep track of you, or weather prediction so you know when best to stop and rest. 
Or since these technologies are so small, why not have a computer surgically placed on your body? I could get an entire computer placed in my body, perhaps for example my arm. Then I could get a foldable screen that receives information from my body and displays it for me. Who knows, perhaps with advancing power supplies, I could run the computer with my own body, never having to recharge it. 
The only question is, how long will it be, and how do I download songs into myself?